High Alumina Refractory Balls for Industrial Furnaces & Reactors

Our high alumina refractory balls are dense, sintered spheres engineered for extreme temperature and chemical environments. Available in 92% and 99% alumina grades with diameters from 3mm to 75mm, these balls provide superior performance as heat exchange media in regenerative burners and as inert support in catalyst beds. Custom dimensions and properties are available to match specific operational requirements.

Catalogue No. AT-YM-H001
Alumina Content (Al₂O₃) 92% – 99.5%
Crushing Strength (per ball) ≥ 8,500 N (for Ø25mm ball)
Maximum Service Temperature 1400°C (92%) – 1730°C (99.7%)
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High alumina refractory balls are heat-resistant ceramic spheres made primarily from high-purity alumina (Al₂O₃ content typically 70–99%). They are designed to withstand extreme temperatures and harsh chemical environments, making them widely used in high-temperature industrial furnaces and chemical reactors.

 

High Alumina Refractory Ball Benefits

  1. High-Purity Raw Materials: Manufactured from calcined alumina powder with minimal silica (SiO₂) content (<0.2% for 99% grade), preventing catalyst poisoning and chemical reactions in sensitive processes.
  2. Superior Mechanical Strength: A unique micro-crystalline structure results in high crushing strength and resistance to abrasion, ensuring bed integrity and minimizing dust formation during operation and loading.
  3. Exceptional Thermal Performance: The high density and specific heat capacity allow for maximum thermal storage in regenerative systems, while excellent thermal shock resistance withstands rapid temperature fluctuations without cracking.
  4. Chemical Inertness: The balls are highly resistant to corrosion from most acids and alkalis (excluding hydrofluoric acid), ensuring long service life in harsh chemical processing environments.

 

High Alumina Refractory Ball Properties

alumina balls size of diameter

Property Unit 99.7% Al₂O₃ 99.5% Al₂O₃ 99% Al₂O₃ 96% Al₂O₃
Color   Ivory White Ivory White Ivory White Ivory White
Density g/cm³ 3.94 3.9 3.83 3.6-3.75
Water Absorption % 0 0 0 0
Hardness Mohs Hardness 9.1 9 9 8.8
Flexural Strength (20°C) Mpa 330 320 300 260
Compressive Strength (20°C) Mpa 2300 2300 2210 1910
Maximum Operating Temperature °C 1730 1700 1680 1450
Thermal Expansion Coefficient(25°C to 800°C) 10⁻⁶/°C 7.6 7.6 7.6 7.6
Thermal Conductivity (25°C) W/(m·K) 29 27 24 22
Dielectric Strength (5mm thickness) AC-kv/mm 22 21 19 15
Dielectric Loss at 25°C@1MHz --- < 0.0001 < 0.0001 0.0003 0.0004
Dielectric Constant at 25°C@1MHz --- 9.8 9.7 9.5 9.2
Volume Resistivity (20°C) Ω·cm³ >10¹⁴ >10¹⁴ >10¹⁴ >10¹⁴
Volume Resistivity (300°C) Ω·cm³ 2*10¹² 2*10¹² 4*10¹¹ 2*10¹¹

 

High Alumina Refractory Ball Specifications

High Alumina Refractory Ball
Item No. Diameter (mm)
AT-YM-H001 0.5
AT-YM-H002 1
AT-YM-H003 2
AT-YM-H004 3
AT-YM-H005 4
AT-YM-H006 5
AT-YM-H007 6
AT-YM-H008 7
AT-YM-H009 8
AT-YM-H010 9
AT-YM-H011 10
AT-YM-H012 11
AT-YM-H013 12
AT-YM-H014 13
AT-YM-H015 14

 

High Alumina Refractory Ball Packaging

  • High alumina refractory balls are packaged in 25 kg heavy-duty plastic bags, which are then placed inside 1-ton jumbo bags with inner waterproof liners. The jumbo bags are palletized and shrink-wrapped for secure, moisture-free international transport.

High Alumina Refractory Ball Packaging

High Alumina Refractory Ball Applications

  • Steel Industry: Regenerative Hot Blast Stoves

    High alumina refractory balls are used as the primary heat exchange media in the regenerators of hot blast stoves.

    ✅Key Advantages

    1. High heat capacity (1.05 J/g·K at 1000°C) maximizes thermal energy stored from flue gas.
    2. Exceptional refractoriness under load prevents deformation under the weight of the bed at temperatures up to 1790°C.
    3. High crushing strength (>8,500 N/ball) resists breakage during thermal cycling, preventing blockage of air passages.

    ✅ Problem Solved

    A European steel mill replaced their lower-grade ceramic balls with our 92% high alumina balls. This change increased the blast temperature by 50°C and reduced the replacement cycle from 24 months to 36 months, preventing an estimated €200,000 in downtime and energy loss over the extended period.

  • Petrochemical Industry: Catalyst Bed Support Media

    Inert 99% high alumina refractory balls are used as the top layer and support material in fixed-bed reactors.
    ✅Key Advantages

    1. Extremely low silica content (<0.2%) prevents contamination and poisoning of sensitive catalysts (e.g., in hydrocracking units).
    2. Uniform spherical shape ensures consistent bed voidage, leading to a stable pressure drop and even flow distribution across the catalyst bed.
    3. High chemical resistance prevents leaching or reaction with process fluids, even under high pressure and temperature.

    ✅ Problem Solved

    A Middle Eastern petrochemical plant was experiencing premature catalyst deactivation. Analysis showed silica leaching from their previous support media. After switching to our 99% alumina balls, catalyst lifetime increased by 30%, saving an estimated $1.2 million per reactor cycle in catalyst and change-out costs.

  • Environmental Technology: Regenerative Thermal Oxidizers (RTOs)

    High alumina refractory balls form the ceramic heat-recovery beds in RTOs used for destroying volatile organic compounds (VOCs).
    ✅Key Advantages

    1. Excellent thermal shock resistance withstands the rapid heating and cooling cycles inherent to RTO valve switching.
    2. High thermal conductivity (25 W/m·K) facilitates rapid heat transfer, enabling thermal efficiencies of up to 97%.
    3. Low porosity and smooth surface minimize the risk of particulate matter buildup, ensuring long-term, low-maintenance operation.

    ✅ Problem Solved

    An automotive paint shop in the USA reported that their RTO, filled with our 92% alumina balls, maintained a consistent 99% VOC destruction efficiency over 5 years of continuous operation, passing all EPA inspections without needing a media change-out.

Usage and Maintenance Guide for High Alumina Refractory Balls

Proper handling and maintenance of high alumina balls will extend their service life and reduce your operational costs.

  • Installation

    1. Before loading, ensure the reactor or furnace support grid is clean and level.
    2. Load the balls carefully to avoid high drop heights, which can cause chipping or cracking. A chute or sock-loading method is recommended.
    3. For mixed-bed applications, load different sizes in distinct layers as specified in the design diagram.

  • Operation

    1. Avoid sudden, extreme temperature shocks during the initial heat-up. Follow a controlled temperature ramp-up schedule (e.g., 50-100°C per hour).
    2. Ensure process gases are filtered to prevent particulate matter from fouling the bed.
    3. Monitor the pressure drop across the bed; a gradual increase may indicate fouling or ball breakage.

  • Storage

    1. Store the balls in their original, unopened packaging in a dry, covered area.
    2. Keep them away from direct contact with the ground to prevent moisture absorption.
    3. Although chemically inert, avoid storing them in areas with high concentrations of corrosive fumes.

  • Cleaning

    1. If cleaning is necessary, use compressed air to remove dust.
    2. For stubborn contaminants, steam cleaning or a controlled burnout procedure may be possible, but consult with our engineers first to ensure the procedure is safe for the material.

  • Common Issues & Solutions

    1. Issue: Increased pressure drop.
    Possible Cause: Ball breakage or particulate fouling.
    Solution: Investigate the top layer for dust. If breakage is suspected, a partial or full replacement may be needed at the next scheduled shutdown. Contact our technical support for analysis.

High Alumina Refractory Ball FAQ

  1. Q: How is the crushing strength of a single high alumina refractory ball measured?
    A: The crushing strength is determined by compressing a single ball between two flat plates at a controlled rate until fracture occurs. The force required for fracture is recorded in Newtons (N). This test is a key indicator of the ball's ability to withstand the static load of the packed bed.
  2. Q: Can these high alumina refractory balls be used in grinding applications?
    A: Yes, our 92% alumina balls, due to their high density and wear resistance, are also effective as grinding media for milling ceramic raw materials and glazes. They offer a good alternative to steel or zirconia balls in certain applications.
  3. Q: What is the typical thermal expansion of a high alumina refractory ball?
    A: The coefficient of thermal expansion for a 92% refractory alumina ball is approximately 8.0 x 10⁻⁶ /°C. This low expansion contributes to its excellent thermal shock resistance.
  4. Q: How do you ensure the diameter consistency of the balls?
    A: Our manufacturing process involves precision forming and automated optical sorting to ensure all high alumina balls fall within the specified diameter tolerance (e.g., ±1.0mm).
  5. Q: Are these refractory balls resistant to hydrogen atmospheres at high temperatures?
    A: Yes, high alumina ceramics are stable in reducing atmospheres, including dry hydrogen, at high temperatures. They will not react or degrade, unlike silica-based refractories.
  6. Q: What is the bulk density of a packed bed of these balls?
    A: The packed bulk density depends on the refractory ball diameter and loading method but is typically in the range of 2.1 - 2.3 g/cm³ (131 - 144 lb/ft³).
  7. Q: How long is the service life of high alumina refractory balls in an RTO?
    A: With proper operation, the service life in a typical RTO application can exceed 5-10 years. The primary life-limiting factors are thermal shock from improper operation and chemical attack from contaminants in the process stream.

What Our Clients Say about High Alumina Refractory Ball

  • ⭐️⭐️⭐️⭐️⭐️
    "We replaced the checker bricks in our stove's upper zone with their 50mm 92% alumina balls. The result was a measurable increase in thermal efficiency. The balls have withstood over 1,000 thermal cycles without significant degradation. A solid product for high-temperature heat exchange."
    -- David Chen, Plant Manager, ArcelorMittal USA
  • ⭐️⭐️⭐️⭐️⭐️
    "The consistency in size and density of the catalyst support media we received was impressive. This uniformity is key for predictable reactor performance. The packaging was robust and suitable for the long sea freight and harsh site conditions here."
    -- Fatima Al-Jamil, Procurement Lead, SABIC Saudi Arabia
  • ⭐️⭐️⭐️⭐️⭐️
    "Our regenerative thermal oxidizer required a full media replacement. We chose their High Alumina Refractory Ball product due to its specified thermal shock resistance. After one year of operation, bed inspection showed minimal chipping and no signs of fouling, maintaining our system's thermal efficiency above 95%."
    --Marek Kowalski, RTO Maintenance Supervisor, Guardian Glass Poland
  • ⭐️⭐️⭐️⭐️⭐️
    "For a new LNG project, we specified a multi-layer bed design requiring different diameters of inert support. The ADCERAX provided three distinct sizes of their High Alumina Refractory Ball, all meeting the stringent dimensional tolerances and crushing strength requirements. Their technical documentation was thorough, which simplified our validation process."
    --Liam Murphy, Engineering Consultant, WorleyParsons Australia
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Customization Services for High Alumina Balls

We provide engineering support to produce high alumina balls tailored to your specific application drawings and process conditions. What you can specify:

1. Alumina Content & Purity

  • Standard Grades: 92% Al₂O₃ for thermal use, 99% Al₂O₃ for high-purity, inert applications.
  • Custom Options: Tailored Al₂O₃ levels (e.g., 95%, 99.5%) with controlled impurities (low SiO₂, Fe₂O₃) to avoid catalyst poisoning.

2. Size & Precision

  • Diameter Range: 3 mm – 75 mm.
  • Tolerance: ±1.0 mm for bulk, ±0.2 mm for precision needs.
  • Sphericity: Controlled roundness for stable packing and flow.

3. Porosity & Density

  • Porosity: <1% for strength, 5–10% for surface area.
  • Bulk Density: Adjustable for heat capacity and strength balance.

4. Surface Finish

  • As-Fired: Cost-effective for general use.
  • Polished: Smooth, low-friction, dust-free for grinding or fluid applications.
  • Custom Ra: For specialized flow control.

5. Mechanical & Thermal Performance

  • Crushing Strength: Defined minimum to prevent breakage under load.
  • Thermal Shock Resistance: Optimized for processes with rapid temperature cycling.

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