Zirconia Toughened Alumina (ZTA) Tube — Industrial & Custom Sizes

ZTA tube for high-wear and high-temperature environments; standard IDs 2–80 mm, length up to 1000 mm; custom wall thickness and tolerances available.

Catalog No. AT-ZRG001
Material 85-90% Al2O3 + 10-15% ZrO2
Flexural strength ~600–900 MPa
Fracture toughness (KIc) ~5–7 MPa·m½
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Zirconia Toughened Alumina (ZTA) tubes are advanced structural ceramics composed of a high-purity alumina (Al₂O₃) matrix reinforced with fine zirconia (ZrO₂) particles. This composite microstructure leverages transformation toughening, where zirconia grains undergo a stress-induced phase transformation that absorbs energy and hinders crack propagation.

 

Zirconia Toughened Alumina Tubes Benefits

  • Crack-tolerant geometry: zirconia toughening reduces edge micro-chipping at ports and tips.
  • Wear-stable bores: high hardness limits diameter drift in abrasive slurries and powders.
  • Dimensional fidelity at heat: low CTE curbs bow and mismatch with metallic fixtures.
  • Consistent insulation: high resistivity and dielectric margin for sensor/heater isolation.
  • Defined temperature window: robust continuous use around 1,000–1,500 °C (by atmosphere).

 

ZTA Tubes Properties

Property Unit Alumina (99%) ZTA (Zirconia Toughened Alumina) Y-TZP Zirconia
Fracture Toughness (KIC) MPa·m¹⁄² 5 7 – 9 6 – 10
Hardness (HV10) GPa 8.9 9 – 10 (≈ 90 HV) 12 – 14
Flexural Strength MPa 400 650 – 800 800 – 1200
Density g/cm³ 3.9 4.0 – 4.3 6.0
Relative Wear Rate 1.0 0.45 – 0.55 0.2
Thermal Expansion Coefficient (RT – 800 °C) ×10⁻⁶ /K 8.0 8.5 – 9.0 10 – 11
Thermal Conductivity (RT) W/m·K 25 22 – 24 2 – 3
Maximum Working Temperature °C 1600 1450 – 1500 1000 – 1200
Dielectric Strength kV/mm 12 11 – 13 9 – 11
Surface Roughness (Ground face) µm Ra 0.4 – 1.2 0.3 – 0.8 0.2 – 0.6
Flatness (after grinding) mm/300 mm ≤ 0.4 ≤ 0.3 ≤ 0.2

 

ZTA Tubes Specifications

 

ZTA Tubes
Item No. Outer Diameter *Inner Diameter(mm) Length(mm)
AT-ZRG001 0.7*0.3 L≤500mm
AT-ZRG002 0.8*0.4
AT-ZRG003 0.9*0.4
AT-ZRG004 1.0*0.5
AT-ZRG005 1.1*0.6
AT-ZRG006 1.2*0.6
AT-ZRG007 1.3*0.7
AT-ZRG008 1.4*0.8
AT-ZRG009 1.5*0.8
AT-ZRG010 2.0*1.0
AT-ZRG011 3.0*1.5
AT-ZRG012 3.0*2.0
AT-ZRG013 4.0*2.0
AT-ZRG014 4.0*3.0
AT-ZRG015 5.0*3.0
AT-ZRG016 5.0*3.5
AT-ZRG017 6.0*4.0
AT-ZRG018 7.0*4.5 L≤800mm 
AT-ZRG019 8.0*4.0
AT-ZRG020 8.0*5.0
AT-ZRG021 9.0*6.0
AT-ZRG022 10.0*4.0
AT-ZRG023 10.0*6.0
AT-ZRG024 10.0*7.0
AT-ZRG025 12.0*4.0
AT-ZRG026 12.0*8.0
AT-ZRG027 14.0*4.0
AT-ZRG028 14*10
AT-ZRG029 15*11
AT-ZRG030 16*12
AT-ZRG031 18*14
AT-ZRG032 20*15
AT-ZRG033 25*19
AT-ZRG034 30*25
AT-ZRG035 40*30 L≤1000mm
AT-ZRG036 44*38
AT-ZRG037 50*40
AT-ZRG038 60*50
AT-ZRG039 70*60 L≤1500mm 
AT-ZRG040 80*70
AT-ZRG041 90*80
AT-ZRG042 100*90
AT-ZRG043 110*100
AT-ZRG044 120*110
AT-ZRG045 150*140
AT-ZRG046 200*190

 

 

Zirconia Toughened Alumina Tube Packaging

  • ZTA Tubes in Carton Padded Trays – Prevent vibration

Zirconia Toughened Alumina Tube Packaging

Zirconia Toughened Alumina Tube Applications

  • Heat-treatment & furnace OEM

    ✅Key Advantages

    1. Bow-resistant guide tubes: low CTE limits thermal stress in long spans.
    2. Crack tolerance under cycling: increased KIc reduces port-edge chipping.
    3. Strength at temperature: high flexural capacity supports loading and handling.

    ✅ Problem Solved

    Replacing alumina guides that chipped every ~10 weeks with ZTA tubes reduced edge-chip incidents by ≈70% over 6 months of 1,200–1,300 °C cycling; straightness held within 0.3 mm per 600 mm.

  • Chemical & petrochemical equipment

    ✅Key Advantages

    1. Erosion control: hard bores resist slurry abrasion.
    2. Dimensional stability: ground Ra holds seal interference over time.
    3. Temperature window: continuous ~1,000–1,400 °C depending on medium.

    ✅ Problem Solved

    A sampling lance operating in silica-laden exhaust streams at 900–1,050 °C suffered rapid seal erosion and frequent maintenance when using standard alumina liners. After switching to ZTA tubes, seal life increased by over 2×, and bore wear dropped to <0.02 mm per 1,000 h. The improved fracture toughness and hardness of ZTA minimized chipping at the seal interface while maintaining tight dimensional stability under cyclic heat. This upgrade significantly extended service intervals and reduced total maintenance costs in continuous high-temperature operations.

  • Instrumentation & sensors (TC/heater)

    ✅Key Advantages

    1. Insulation: high resistivity with dielectric margin.
    2. Low CTE: protects hot junctions from sleeve pinch.
    3. Closed-end tips: gas-tight protection in oxidizing atmospheres.

    ✅ Problem Solved

    In a cyclic furnace, frequent thermocouple failures occurred due to cracking and oxidation of standard alumina tubes during repeated heat cycles. After switching to ZTA closed-end tubes, the mean time to failure (MTTF) increased from approximately 3 months to 8 months. The improved fracture toughness (≈6 MPa·m½) and thermal shock resistance of ZTA prevented tip cracking and seal leakage under rapid heating and cooling. This enhancement greatly improved furnace uptime stability and reduced replacement frequency in high-temperature sensor assemblies.

ZTA Tubes Usage Instructions

  • Installation Guidelines

    1. Support method: For tubes longer than 300 mm, use minimum three-point supports or ceramic saddles to prevent bending and local stress. Avoid metal set-screws or rigid clamping that may cause micro-cracks.
    2. Alignment: Ensure coaxial alignment between tube and mating components. Misalignment over 0.2 mm can create stress concentration during heating.
    3. Sealing interfaces: When assembling into housings or fittings, use soft gasket materials such as graphite or PTFE to absorb thermal expansion differentials.
    4. End closure: For one-end-closed tubes, always orient the closed tip toward the heat zone to prevent trapped pressure build-up during heating.
    5. Preheat condition: To minimize thermal shock, preheat gradually at ≤ 3 °C/min from room temperature up to 300 °C before full-power ramp.

  • Usage Recommendations

    1. Temperature range: ZTA tubes are suitable for continuous operation at 1,000–1,500 °C, depending on environment. Avoid direct flame impingement beyond 1,600 °C.
    2. Atmosphere control: In reducing or moist atmospheres, long-term use above 250 °C can affect zirconia stability—ensure dry or neutral gas flow.
    3. Pressure & flow: For pressurized or flow systems, confirm wall thickness and length comply with mechanical limits (consult design chart if > 0.3 MPa).
    4. Thermal cycling: Limit fast quenching or cooling rates; ensure ≤ 5 °C/s gradient between tube surface and core.
    5. Contact materials: Avoid metal contact at red-hot state; differential expansion may seize or fracture the ceramic.

  • Storage & Handling

    1. Storage environment: Keep tubes in a dry, clean, vibration-free area; ambient humidity ≤ 60 %.
    2. Protection: Cap both ends with soft plugs or sleeves to avoid dust ingress or edge damage.
    3. Stacking: Store horizontally on foam or felt-lined racks; never stack bare tubes directly together.
    4. Handling: Always handle using both hands and support across the middle, not by the ends, especially for long thin-walled tubes.

  • Cleaning & Maintenance

    1. Routine cleaning: Wipe surfaces with lint-free cloth and alcohol or neutral detergent.
    2. Heavy contamination: Use alumina or silicon carbide abrasive media for gentle blasting; avoid metallic brushes or acids containing HF.
    3. Internal cleaning: For small-ID tubes, use ceramic or nylon rods with mild abrasive paste to remove scale.
    4. Re-polishing: Light surface regrinding (Ra ≤ 0.8 µm) can restore sealing smoothness.
    5. Inspection interval: Visually check for hairline cracks, edge chipping, or discoloration after every major cycle (> 500 h). Replace if cracks > 0.3 mm or distortion > 1 mm per 500 mm length.

Zirconia-toughened Alumina Tube FAQ

  1. Q: What are the main advantages of using a ZTA tube over pure alumina or zirconia?
    A: ZTA tubes combine the hardness and chemical stability of alumina with the crack resistance of zirconia, providing a balanced performance in strength, wear resistance, and thermal shock tolerance.
  2. Q: What is the maximum operating temperature for ZTA tubes?
    A: They can operate continuously between 1,000–1,500 °C, depending on atmosphere and wall thickness. Above 1,500 °C, the zirconia toughening effect gradually decreases.
  3. Q: What typical mechanical properties does a ZTA ceramic tube have?
    A: Flexural strength: 600–900 MPa, Fracture toughness: 5–7 MPa·m½, Hardness: ≈ 16 GPa, Thermal expansion: 7–8.5 × 10⁻⁶ /K.
  4. Q: Can a ZTA tube replace an alumina tube directly?
    A: Yes, in most applications. The outer dimensions and fittings are compatible, but confirm CTE and tolerance to ensure proper sealing alignment during replacement.
  5. Q: Are ZTA tubes suitable for thermocouple protection?
    A: Yes, especially closed-end ZTA tubes, which provide electrical insulation, gas-tight sealing, and resistance to thermal shock in cyclic furnaces.
  6. Q: What length and diameter range can you manufacture?
    A: We supply 2–80 mm inner diameters, wall thickness from 0.5–10 mm, and lengths up to 1000 mm (longer by assembly).

Zirconia-toughened Alumina Tube Reviews

  • ⭐️⭐️⭐️⭐️⭐️
    “We’ve integrated ZTA ceramic tubes into our furnace thermocouple assemblies. After six months, dimensional drift is nearly zero, and replacement frequency dropped significantly.”
    -- Michael R. Process Engineer, Thermion Heat Systems (USA)
  • ⭐️⭐️⭐️⭐️⭐️
    “The zirconia toughened alumina tubes from ADCERAX maintained excellent surface finish and tolerance. Packaging and quality consistency across batches were impressive.”
    -- Hiroko S. Materials Manager, Kensei Industrial (Japan)
  • ⭐️⭐️⭐️⭐️⭐️
    “Our lab used ZTA tubes for cyclic oxidation tests up to 1,450 °C. No microcracks appeared even after repeated heating and cooling, proving their superior thermal shock resistance.”
    -- Liam G. Project Buyer, EuroChem Equip (Germany)
  • ⭐️⭐️⭐️⭐️⭐️
    “Custom ZTA tubes with O-ring grooves fit perfectly into our pump sealing system. They extended seal life by over 40%, reducing downtime in our chemical process lines.”
    -- Carla M. R&D Lead, NovaLab Instruments (UK)
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Customize Zirconia Toughened Alumina Tube (ZTA) Tube

Specify what you need; we manufacture to drawing or sample.

1. ID/OD & Tolerances

  • Machined strictly to print or draw.
  • Standard precision: ±0.10 mm; fine tolerance: ±0.05 mm achievable.
  • Concentricity & straightness maintained within ≤0.2 mm per 500 mm length.

2. Length Range

  • Single-piece tubes up to 1000 mm.
  • Longer assemblies are available with precision joint design or alignment sleeves.

3. End Configurations

  • Open–Open Type: for general flow or guiding applications.
  • One-End-Closed: flat, domed, or hemispherical for thermocouple and protection use.
  • Customized Ends: sloped, beveled, or grooved with O-ring seat for gas-tight sealing.

3. Cross-Section Options

  • Round (standard) for flow and protection tubes.
  • Multi-bore for multiple sensor leads or heating elements.
  • Square/Rectangular Channels for custom fixtures or high-stability mounting.

4. Wall Thickness Range

  • 0.5–10 mm, depending on OD and mechanical load requirement.
  • Thin-wall designs available for quick thermal response; thick-wall for pressure or impact loading.

5. Surface Finish Options

  • As-fired surface: cost-efficient, suitable for general thermal insulation.
  • Ground / polished: Ra ≤ 0.8 µm on sealing or sliding zones to reduce friction and leakage.
  • Optional sandblasted matte finish for bonding or coating applications.

6. Material Variants

  • Al₂O₃/ZrO₂ ratios: 85/15, 80/20, or custom formulations to balance toughness and expansion.
  • Stabilized zirconia (Y₂O₃- or MgO-stabilized) is available for enhanced phase stability during long-term high-temperature operation.
  • High-purity alumina base (≥99.5%) ensures chemical and thermal reliability.

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